Supercapacitors (SCs) have attracted great attention to solve global energy storage problems. SCs store electrical energy through two charge storing mechanisms: (i) electrical double layer capacitance (EDLC) (electrostatic surface adsorption of electrolyte ions) and (ii) electrochemical redox reactions (pseudocapacitance). An ideal SC should bridge the gap between a capacitor and a battery by offering enormous power density, high energy density, fast charging/discharging capabilities and outstanding lifespan. Typical SCs are based on sandwich-type assemblies, possessing 2D planar geometries. These limitations hinder their applicability as a source of continuous and stable power supply. In fact, poor energy storage performance of SCs is caused by the following factors: (a) inadequate materials (inaccessible active sites) (b) restricted electrode design, therefore (c) low mass loading and (d) inefficient mass/charge transport. This two-fold problem of electrode materials and electrode architecture should be solved within a single system to obtain high-performance SCs. By employing metal organic frameworks (MOFs), their hybrids, and derived composites, this project aims at addressing 4 following challenges regarding electrode materials and their architectures in a holistic way: (1) optimal morphologies and appropriate (micro-meso-macro) pore structures of electrode materials for high power density (EDLC); (2) efficient electrochemical redox activities for high energy density (pseudocapacitance); (3) regulated and reproducible electrode geometries (device scale); and (4) electrically conducting and mechanically stable 3D printed free-standing SC electrodes (atom-to-device-scale). Stereolithographically (SLA) printed metal-organic frameworks/photopolymer resin composites (lithoMOFs) will be ideal precursors to derive high surface area, homogeneous (multi)MO/C composite SC electrodes with hierarchical (micro-meso-macro)pores, accessible active sites, tailored chemical functionalities and customized geometries via simple one-step pyrolysis. For this purpose, we will synthesize rationally designed MOFs to develop stereolithographically 3D printed (MOF derived) metal oxide/carbon composite freestanding electrodes. Bridging two key aspects of electrode material and electrode architecture, this scientific strategy will combine distinct fields of organometallic and coordination chemistry and additive manufacturing (AM).